ABSIRACI After 15 minutes, 1 12 of the photosynthate fixed by isolated chloroplasts of Codium fragile was released to the control medium The percentage released remained constant over a five hour period. Chloroplasts incubated in homogenates of Cfragile did not release a greater percentage of fixed carbon over chloroplasts incubated in the control medium. Extracts from Elysia hedgpethi that were starved for 16 days also did not induce the release of photosynthate from isolated chloroplasts. Further experiments were done using E hedgpethi that were starved for 22 days and then re-fed Cfragile until their green color was restored (7 days). Homogenates of the re-fed slugs again showed no increase in the percentage of fixed carbon released. In one experiment using extracts from Aplysiopsis smithi, 52.3% of the photosynthate was released from isolated chloroplasts, over 2.5 times the percentage released to the control medium. INTRODUCTION The sacoglossan Elysia hedgpethi is known to incorporate chloroplasts from the siphonaceous alga Codium fragile within the cells of its digestive diverticula (Greene, 1970b). It has been shown that the chloroplasts taken up by the animal remain photosynthetically active after incorporation into the animal (Greene, 1970a: Greene and Muscatine, 1972). Studies done on Elysia viridis, another sacoglossan, demonstrate that the chloroplasts of Cfragile are likewise incorporated into the digestive cells and continue to photosynthesize at rates comparable to those in the intact alga (Trench et al., 1973b). Further investigations by Trench, Boyle and Smith (1973b) indicate that 368 of the photosynthate fixed by the ingested chloroplasts is released to the animal tissue. Trench et al. (1973b) found that a greater percentage of fixed carbon was released from chloroplasts incubated in Eviridis homogenates when compared with the percentage released from chloroplasts incubated in simple mineral solution. This suggests that the animal homogenate contains a factor which modifies the permeability of the chloroplast envelope and hence, stimulates the release of fixed carbon. Gallop (1974) reported that the activity of the photosynthate release factor was reduced significantly when chloroplasts were incubated in homogenates from the non-chloroplast bearing tissues of Eviridis. It has therefore been proposed that the presence of chloroplasts within the digestive cells of symblotic sacoglossans is necessary for the synthesis of the release factor (Gallop, 1974). The studies presented here examine the activity of the photosynthate release factor in Ehedgpethi when the digestive cells are lacking chloroplasts versus its activity once chloroplasts have been restored. To further investigate the relationship between the photosynthate release factor in sacoglossan homogenates and symbiotic chloroplasts, a comparative study was done using the homogenate from Aplysiopsis smithi, a sacoglossan unable to retain chloroplasts in its tissues. MATERIALS AND METHODS Collection and Maintenance of Animals: E hedgpethi were collected on Cfragile in Santa Barbara. he animals were maintained without food in a running sea water aquarium illuminated with a battery of fluorescent lamps. Several animals were starved for 22 days then transferred to an aerated beaker containing filtered sea water and fresh Cfragile where they were allowed to feed for 7 days. Aplysiopsis smithi were collected from the mud flats at Noss Landing State Beach (California). These animals were maintained in a running sea water aquarium on a diet of Cfragile and Bryopsis corticulans Collection of C fragile: Fresh C fragile was collected for use in each experiment from the rocky intertidal zone at Hopkins Marine Station, Pacific Grove. Chloroplast Isolation: Chloroplasts were isolated from intact Cfragile using the procedure developed by Shephard et al. (1968) with the following modifications. After resuspending the initial pellet in 10 ml washing medium, the suspension was spun at approximately 800 g for 4 minutes. The supernatant was then spun at 1000 g for 10 minutes (Shephard et al., 1968). Äfter discarding the new supernatant fraction, the pellet was resuspended in 10 ml washing medium and spun at approximately 800 g for 4 minutes as before. The chloroplast suspension was again spun at 1000 g for 10 minutes, the supernatant discarded and the pellet resuspended in the final chloroplast isolation medium containing: mannitol 0.6 M; potassium dihydrogen orthophosphate 10°9 M; hepes 5 x 10-3M potassium chloride 10°2 M; magnesium chloride 5 x 10°9 M; adjusted to ph 7.2. Preparation of Sacoglossan Homogenate Whole animals were homogenized with a Dounce homogenizer at a final concentration of 75 mg wet weight animal/ mi chloroplast isolation medium (see above). Crude homogenates were then centrifuged at 41,000 g for 60 minutes (4°) and the supernatant used for the experimental incubation medium (Gallop, 1974). Preparation of C fragile Homogenate: C fragile fronds were minced with a razor blade, homogenized in a Potter- Elueham homogenizer, then centrifuged at 1700 g for 15 minutes (4°C). The supernatant was the homogenate fraction tested. Assay of Photosynthate Release Eactor Actwity Chloroplasts suspended in isolation medium were incubated with Nah'4coz (10 uC1/m1) for 2 hours at saturating photosynthetic irradiance (R. Zimmerman, personal communication). The amount of radjoactive carbon fixed by chloroplasts incubated in the light was greater than the amount of radioactive carbon fixed by chloroplasts incubated in the dark by a factor of 13.7. Chloroplasts were then collected by centrifugation (12,000 g, 2 min), washed in fresh isolation medium, resuspended in the desired experimental homogenate and incubated for 60 minutes at room temperature. In control experiments, chloroplasts were incubated in isolation medium at the same final chlorophyll concentration. After 60 minutes, the suspensions were pelleted down (12,000 g, 2 min), the supernatants acidified and counts of radioactive carbon measured (see below). The pellets were resuspended in 1 m1 95% hot methano to extract the remaining photosynthate. Chlorophyll Estimation: Ope volume of chloroplast suspension was added to 9 volumes cold acetone then centrifuged at 3900 g for 10 minutes. The amount of extracted chlorophyll was calculated by measuring the absorbance of the supernatant at 663 nm (effrey, 1968). The reading was then standardized by the following equation: OD reading (mMolar)/ 75.05/ 1000 x MW Chlorophylla (893.53 g/mol) x 10 (dilution factor) = (chlorophylD mg/ml. Estimation of Eixed Carbon: Supernatant fractions from the incubation media, washings and extracted pellets were transferred to a 24-well plastic culture dish. To drive off residual radioactive bicarbonate the solutions were made 102 in trichloroacetic acid (TCA) and shaken vigorously for 15 minutes. The acidif ied fractions were mixed with 5 ml scintillation fluid and the radioactivity analyzed with a Beckman scintillation counter. RESULIS Analysis of Photosynthate Released Over Iime: Chloroplasts containing radioactive photosynthate accumulated over 2 hours were resuspended in fresh isolation medium and incubated at room temperature. At times 15, 30, 45, 60, 90, 120, 180, and 289 (in minutes af ter resuspension) aliquots of the suspension were centrifuged and the supernatant and pellet fractions analyzed for radioactivity (figure 1). The results indicate that the amount of fixed carbon leaked to the suspension medium reaches a maximum value by 15 minutes with no further increase over 5 hours. Effect of C fragile Homogenate on the Release of Photosynthate from Isolated Chloroplasts. When chloroplasts containing radioactive photosynthate were incubated in Cfragile homogenate they did not produce a greater release of fixed carbon in comparison to chloroplasts incubated in the control medium (Table 1 ). Effect of Starved E hedgpethi Homogenate on the Belease of Photosynthate from Isolated Chloroplasts: Chloroplasts incubated in the homogenate from E hedgpethi that were starved for 16 days show no significant difference in the percentage of fixed carbon released when compared with control medium incubation (Table 1). Effect of Re-fed E hedgpethi Homogenate on the Release of Photosynthate from Isolated Chloroplasts: The homogenate from animals that were starved of chloroplasts and then re-fed Cfragile does not enhance the percentage of fixed carbon released to the incubation medium (Table 1). Effect of A smithi Homogenate on the Belease of Photosynthate from Isolated Chloroplasts. These results demonstrate a marked increase over control values in the amount of fixed carbon released when chloroplasts were incubated in A smithi homogenate (Table 1). DISCUSSION When labeled, isolated chloroplasts are incubated in the supernatant of Cfragile homogenate there is no greater release of fixed carbon than occurs in control medium incubation. This could suggest that the mechanism for release of photosynthate in intact Cfragile is lost when the alga is homogenized. Alternatively, it is conceivable that no such release factor is synthesized by C fragile Le., the intrinsic release rate of photosynthate is sufficient to meet the plant's needs. An informative experiment would be to determine whether the time course of release of photosynthate from chloroplasts incubated in Cfragile homogenates is similar to that in control medium. The experiments with Ehedgpethi show no evidence for the presence of a photosynthate release factor in the homogenates of the starved animals nor in the homogenates of the re-fed animals. However, previous reports indicate that such a factor is found in the homogenates of E viridis (Trench et al. 1973b). Evidence for the presence of such a release factor in Ehedgpethi is presented in a recent study done by Francis Glaser (unpublished) who reports an increase in the amount of photosynthate released from chloroplasts incubated in E hedgpethi homogenates over the values demonstrated by control medium incubation. From these experiments ! conclude that the release factor is synthesized only when chloroplasts are present in the digestive diverticulum of Ehedgpethi and fürther, that this release factor is broken down when chloroplasts are lost from E hedgpethi upon starvation. It is possible that more than 7 days are required for the release factor to achieve a quantity sufficient to yield à measureable effect on the release of photosynthate. Yet, in a presentation by Mart in Kozdrowicki on June 3, 1988 (Symposium of the China Point Academy of Sciences - XXIV Annual) it was announced that the chlorophyll content of Ehedgpethi starved free of chloroplasts and then re-fed on Cfragile for 7 days was equivalent to the chlorophyll content of animals that had not been starved. Perhaps there is both a minimum chlorophyll concentration and a minimum time period required for the activity of the photosynthate release factor to be regained. More likely, the release factor was destroyed during incubation. Glaser (personal communication) reported that the activity of the release factor was severely diminished after Ehedgpethi homogenates were incubated for one hour at room temperature, the temperature at which! conducted my incubations. Data collected from A smithi homogenates strongly suggest the presence of a photosynthate release factor. Unlike that of E hedgpethi homogenates, the release factor of A smithi homogenates, if such a factor exists, is not destroyed by incubation at room temperature. However, since Asmithi are incapable of incorporating chloroplasts (R. Swezey, personal communication) it may be that this sacoglossan homogenate contains damaging digestive enzymes which lyse chloroplast envelopes. To test this the supernatant from chloroplasts incubated in A smithi extracts should be measured for absorbance at 663 nm. A strong absorbance would be indicative of chlorophyll in the supernatant and can be interpreted as lysis of the chloroplasts (Denis Larochelle, personal communication). In addition, the functionality of chloroplasts should be tested after incubation in A smithihomogenates i.e., the amount of labeled carbon fixed by chloroplasts incubated in A smithi homogenates should be compared to the amount of radioactive carbon fixed by chloroplasts of the control medium incubation. when ! tested the control medium and the medium from re-fed E. hedgpethi homogenate for chlorophyll the results were negative. Furthermore, chloroplasts incubated in homogenates of E hedgpethl showed the same photosynthetic ability as chloroplasts incubated in control medium (F.Glaser, personal communication). Thus, it is evident that the release of photosynthate is not due to severe lysis of the chloroplast envelope when chloroplasts are incubated in E hedgpethi homogenates. The incubations of chloroplasts in E hedgpethi extracts should be repeated at 17 °C to compare with data collected by Glaser and others. Finally, to help clarify the limitations of using tissue extracts to study living systems, further investigations should ipvolve invivo studies on the release of photosynthate from the symbiotic chloroplasts of E hedgpethi. SUMARY The amount of photosynthate released from chloroplasts to the isolation medium reaches a maximum value in 15 minutes. Homogenates from starvedE hedgpethi and re-fed Ebedgpethi did pot demonstrate the ability to release fixed carbon from isolated chloroplasts, whereas chloroplasts incubated in the homogenate of A.smithireleased 52.3% of the total labeled photosynthate, over 2.5 times the percentage released in the control incubation. Acknowledgements: Iwould like to thank Dr. Robert R. Swezey for his support and enthusiasm and for the many hours he devoted to this scientific endeavor. Special thanks to Denis Larochelle for all of his help and to Dr. David Epel for granting the use of his laboratory, making this research possible. 12 REEERENCES Gallop, A. (1974). Evidence for the presence of a' factor' in Elysia viridis which stimulates photosynthate release from its symbiotic chloroplasts. New Phytol, 73, 1111. Greene, R. W. (1970 a). Symbjosis in sacoglossan opisthobranchs: Translocation of photosynthetic products from chloroplast to host tissue. Halacologia, 10, 369. Greene, R. W. (1970 b). Symbiosis in sacoglossan opisthobranchs: Symbiosis with algal chloroplasts. Malacologia, 10, 357. Greene, R. W. & Muscatine, L. (1972). Symbiosis in sacoglossan opisthobranchs: Photosynthetic products of the chloroplasts. Mar Biol, 14, 253. Jeffrey, S. W. (1968). Pigment composition of siphonales algae in the brain coral Eavia. BiolBulL, 135, 141. Shephard, D. C., Levin, W. B. & Bidwell, R. G. S. (1968). Normal photosynthesis by isolated chloroplasts. Biochim biophys Acta, 32,413. Trench, R. K., Boyle, J. E. & Smith, D.C. (1973 b). The association between chloroplasts of Codium fragile and the mollusc Elysia viridis: II. Chloroplast ultrastructure and photosynthetic carbon fixation in Eviridis. Proc R. Soc Lond. B., 184, 63. 6 CO O + 0 NO — Z de FIGURE 1. RELEASE OF PHOTOSYNTHATE FROM CHLOROPLASTS IN ISOLATION MEDIUM Chloroplasts containing photosynthate accumulated over 2 hours were resuspended in fresh isolation medium then incubated at room temperature. At times 15, 30, 45, 60, 90, 120, 180, and 289 (in minutes after resuspension) aliquots of the suspension were centrifuged and the supernatant and pellet fractions analyzed for radioactivity. Figure 1. is a plot of the percentage of fixed carbon released to the isolation medium at each time point tested. 0- o I 81 % FIXED CARBON RELEASED — O 15