ABSTRACT Stimulation of NIE-115 mouse neuroblastoma cells with the neurotransmitter bradykinin (Bk) leads to inositol 1,4,5-trisphosphate (IPz) production and calcium release from IPz-regulated Ca“ pools located in the endoplasmic reticulum. This involves a specific G-protein second messenger cascade. The release of intracellular Ca“ is preceded by a latent period of up to 30 seconds. This study investigated the contribution of IPz diffusion and the dynamics of IP; receptor activation to the latency between surface receptor binding and Ca- release. Intracellular injection of caged IPz plus the fluorescent calcium indicator fluo-3 was used investigate the basis of the observed latency. Following injection, cells were exposed to a brief (170us) flash of light (230 joules, 360nm wavelength) to photolyse the caged compound. Fluorescence video imaging was used to follow the change in intracellular [Ca. The study showed that [Ca begins to rise immediately (within 200ms) following uncaging of IPz by flash photolysis, and reaches maximum levels within 1.5 seconds. The result indicates that neither IPz diffusion to its receptors nor delay between IP3R activation and Ca" release contribute significantly to overall latency. Analysis of Ca“ wave kinetics shows that in contrast to cells stimulated with neurotransmitter, injected cells do not exhibit propagation of Ca“ waves following photolysis of caged IPz. This observation suggests that the IPz receptor is distributed throughout the cytoplasm of the soma and major neurites. Ca“ waves apparently travel through this IPz receptor rich medium. The constant rate in which Ca“ waves travel shows that propagation is an active process rather than a diffusional process. The mechanism of propagation could involve either IPz production or Ca"-induced Ca- release at the wave front. INTRODUCTION Metabotropic neurotransmitter receptors are linked via second messenger pathways to their intracellular effector targets. The bradykinin (Bk) B2 receptor subtype is coupled by the G- protein Gyii to a wide variety of second messenger cascades, with one prominent effect being the activation of the membrane-bound enzyme phospholipase C (PLCB1). PLC hydrolyzes phosphotidyl inositol 4,5-bisphosphate (PIP2) in the plasma membrane to form inositol 1,4,5- trisphosphate (IPz) and diacylglycerol (DAG) [Rhee et al., 19891, both of which act as intracellular messengers. IPz diffuses in the cytosol to receptors on the surface of the endoplasmic reticulum. Activation of the IPz receptor leads to release of Ca into the cytosol from Ca storage compartments of the endoplasmic reticulum. Surface receptors coupled to second messenger pathways characteristically mediate responses which are slow in both onset and duration [Hartzell, 1981]. Response latencies as long as 30 seconds in duration have been observed for B2 receptor activation in neuroblastoma cells [Coggan et al., 1995]. The existence of such an appreciable delay between surface receptor binding and cellular response has important consequences for the synaptic activation of cells Described here is an investigation of possible origins of the latency of responses mediated by the phosphoinositide signaling pathway in NIE-115 mouse neuroblastoma cells, a sympathetic neuronal cell line which express a number of G-protein coupled receptors including B2, Hj, Mi, and Ma receptors. It has been suggested that the limiting factors determining response latency at high agonist concentrations arise from stages in the phosphoinositide signaling cascade located between receptor binding and IPz liberation. It was further suggested that at low agonist concentrations, an additional delay is introduced due to intracellular levels of IPz rising slowly to a threshold before triggering calcium release [Miledi et al., 1988). To test the prior theory, NIE-115 cells were intracellularly injected with a photo-releasable IPz (caged IPz) and an appropriate fluorescent Ca indicator (fluo-3) Photolabile caged compounds are inert precursors of biologically active molecules that can be loaded into cells and subsequently released in their active form. Uncaging is accomplished by a flash of light (360nm) that triggers the breaking of photolabile bonds to release the bioactive molecule. The absorption of photons excites the inert parent compound to a higher energy state where it undergoes a reaction leading to the formation of a stable, physiologically active biomolecule. Measurements of response latencies evoked by intracellular injection of bioactive molecules are complicated by uncertainties regarding micropipette tip positioning, and also by the difficulty in controlling injection volume. The use of caged compounds results in more accurate measurements by eliminating such uncertainties, and by presenting the opportunity of both controlling release and guaranteeing even distribution throughout the cell by simple diffusion [Miledi et al., 19881 In this study, injected caged IPz was released by flash photolysis and changes in latency preceding Ca“ release from internal stores was measured through fluo-3 imaging. The results were then compared to response latency measured following surface receptor stimulation with bradykinin. The objective was to determine whether the time of IPs diffusion to its receptors on the ER and/or delay between receptor activation and Ca“ release significantly contributed to the overall response latency. IPz has been shown to have a measured diffusion coefficient (D) of 283um'/s and a effective range lifetime of 24um [Allbritton et al., 19921. Thus for cells smaller than 20um, IPz acts as a global messenger. IPz-dependent Ca“ release occurs in an organized manner, often taking the form of a wave passing throughout the cell [Gilkey et al., 1978). Investigation into the Ca* wave phenomena following agonist stimulation has led to a theory of wave propagation that relies on the observation that Ca“ itself can act as a coagonist in triggering IPz-induced Ca- release Finch et al., 1991). The model suggests a positive feedback loop that operates when intracellular IP, levels are at threshold and if IPz-bound receptors are spaced closely enough that Ca- release beginning at one receptor can bring neighboring IPz receptors to threshold for Ca release. The local increase in Ca“ allows for further propagation of the Ca“ wave as the cycle continues down the length of the cell [Wang et al., 1995). To test the model's assumption that IPz receptors are distributed throughout the cell, analysis of wave propagation kinetics was conducted on cells intracellularly injected with caged IPz. MATERIALS AND METHODS Cell Culture NIE-115 mouse neuroblastoma cells were obtained from the UCSF Cell Culture Facility, maintained without antibiotics in Dulbecco's Modified Eagle Medium (Sigma Chemical Co., St. Louis, MO) supplemented with 10% bovine serum, and grown to passages 6-8. For experimentation, cells were plated on glass coverslips. To initiate differentiation, the medium was replaced with medium containing 2% dimethylsulfoxide. Cells were used 6-14 days following differentiation [Wang et al., 19951. Microinjection of cells After rinsing in Hank's buffer, pH 7.4, the cells were transferred to a heated chamber (30°C) for microinjection. FFP-18, K salt (TEFLABS, Austin, TX) and fluo-3, pentaammonium salt (Calbiochem-Novabiochem Corp., La Jolla, CA) were injected at 1mM concentrations using an Eppendorf micromanipulator 5171 (Eppendorf-Netheler-Hinz GmbH, Hamburg, Germany). D-myo-Inositol 1,4,5-trisphosphate, P“-1-(2-nitrophenyl) ethyl ester, sodium (caged IPz, trisodium salt - Calbiochem-Novabiochem Corp., La Jolla, CA) and fluo-3, pentaammonium salt (Calbiochem) were each dissolved at concentrations of ImM in saline containing SmM HEPES, pH 7 at 20°C and microinjected using the Eppendorf micromanipulator. Injected caged IPz was allowed to evenly distribute throughout the cell for 10 minutes or more. Assuming that injection volumes were no more than 10% of the total cell volume, the concentration of each compound in cells was no more than 1OOUM. AM loading of cells Cells were loaded with the low-affinity Ca" indicator mag-fura-2 by incubation in saline containing 5uM mag-fura-2/AM and 0.0025% Pluronic F-127 (Molecular Probes) for 45 minutes at 22°C. Calcium imaging Following loading, cells were transferred to a heated chamber (30°C) on the stage of a Nikon Diaphot epifluorescence microscope with 20x and 40x Fluor objectives (Nikon), Hamamatsu C2400 silicon-intensified target camera, and a Panasonic VHS video tape recorder. Excitation illumination by a Xenon arclamp was filtered through lOnm bandpass interference filters at 340 or 380nm wavelengths for FFP-18 and 525nm wavelengths for fluo-3. Wave analysis was done off-line on a Mega Vision 1024XM pipeline image processor (Mega Vision, Santa Barbara, CA) frame by frame from data transferred from tape to a Panasonic TQ-2028F optical disk recorder. For FFP-18 injected cells, Ca“ kinetics were determined by monitoring cells continuously for up to 60 seconds at 380nm excitation after initially obtaining Fzao/F3so. For fluo-3 injected cells, Ca kinetics were determined by monitoring cells for up to 60 seconds at 525nm excitation wavelengths. For caged IPz + fluo-3 injected cells, a brief (170us), maximum intensity flash (230 Joules, 360nm) from a Xenon Strobex lamp (Chadwick-Helmuth Co., El Monte, CA) was focused directly onto the cell field to photolyse the caged IPz. Following flash illumination, Ca- kinetics were resolved by monitoring cells for up to 30 seconds under 525nm light. A stroboflex shutter was closed during the flash to protect the SIT camera. The reopening of the shutter is associated with a time delay of 100ms. An additional delay of approximately 200ms is associated with the delay in camera response time following shutter reopening. Neurotransmitter application Bradykinin (1OOnM) was applied by total replacement of the chamber volume using a manually-controlled perfusion device. Calcium and calcium wave analysis Increases in intracellular Ca“ were observed following stimulation with 100nM bradykinin. Responsive cells were identified by eye, reviewing the data played back at 1-4 times normal speed. Changes in [Ca“ were measured in regions of interest corresponding to the center of individual cell bodies. Baseline fluorescence, Fo, was defined as the average fluorescence within the region of interest over 5-10 frames just prior to agonist application. The fluorescence signal was converted to units of AF/F. Ca“ waves were evoked in similar fashion as changes in intracellular Ca“. Waves were identified by eye, viewing data played back at 1-4 times normal speed. For quantitative analysis of wave motion, a line segment passing through the cell in the direction of wave propagation was selected. Fluorescence was averaged over 1 to 3 pixels on either side of the line at a rate of 30 frames per second. Normalized lines of AF were stacked to generate images in which the y-axis represented time and the x-axis represented location along the scanned line segment, yielding a graph of wave position against time. RESULTS Properties of Ca indicators Due to the wavelength needed to release caged IPz, my studies used fluo-3 as a fluorescent Ca“ indicator. Fluo-3 is excited at longer wavelengths (525nm) than fura-2 and related indicators (FFP-18, mag-fura-2), which are excited in the 340-380nm range, the same spectral range in which caged compounds are photo-released. The lipophilic tail of FFP-18 allows it to function as a near-membrane Ca“ indicator upon injection, allowing one to take advantage of the fact that Ca“ levels near membranes rise faster and higher than in the cytosol. Mag-fura-2, a low-affinity Ca“ indicator, presents the advantage of exhibiting spectral shifts at higher Ca- concentrations (up to 100uM), allowing resolution of greater peaks in [Ca following stimulation. Latency following bradykinin stimulation The activation of B» receptors by bradykinin in cells injected with FFP-18 (ImM micropipette concentration) or mag-fura-2 (lmM) results in a latent period (mean latency = 9.06 seconds) preceding a rise in intracellular [Ca (Fig. 1-2). [Ca increases to approximately 2uM (an estimated 20 fold increase from resting Ca“ levels) within 2-5 seconds following initial response. The increase in [Ca is followed by a characteristic falling phase where fluorescence exhibits a smooth decay to resting levels. The decay of mag-fura-2 appears more rapid than the decay of FFP-18. The high affinity of FFP-18 for Ca“ causes it to reach saturation well before peak Ca is attained, accounting for the slower apparent decay of the signal. Latency following flash photolysis of caged IP; Flash photolysis of cells injected with caged IPz plus fluo-3 (ImM micropipette concentrations) does not exhibit a latent period prior to the rise in intracellular [Ca (Fig. 3). Photolysis occurs instantaneously following shutter closure (see Materials and Methods) and is represented by a decline in fluorescence. Response to uncaging in the single cell, illustrated in Fig 3., is characterized by an immediate rise (within 200ms) in [Ca, with peak levels reached in less than 1 second. Peak [Ca corresponds to approximately 600nM (an estimated 6 fold increase from resting levels). An averaged response to flash photolysis of caged IPz (Fig. 4) shows similai results, but exhibits a noticeably slower rise to maximum Ca“ levels (2-3 seconds following photolysis). The attainment of peak [Ca is followed by a falling phase where fluorescence exhibits exponential decay to resting levels (Fig. 5). The time to one-half decay was measured to be 4.06 seconds. Kinetics of rising phase following flash photolysis Analysis of the response kinetics following flash photolysis reveals a 200ms period where Ca“ imaging is not recorded (Fig. 6). The shutter reopening and delay associated with camera response accounts for this lag period (see Materials and Methods). Recording begins within 1 second at which time [Ca are near peak levels. Thus, the initial rising phase following photolysis is undocumented due to recording limitations. An average of response kinetics to uncaging of IPz (Fig. 7) shows the same 200ms loss in imaging, but a slightly longer time interval to peak [Ca of 2-3 seconds following uncaging. Comparison of latency following agonist stimulation A comparison of latencies to Ca“ release in the same neuronal cell following flash photolysis of IPz and stimulation with bradykinin is shown in Fig. 8. Flash photolysis of IPz results in a rise in intracellular [Ca within 200ms of uncaging. In contrast, stimulation with bradykinin results in a latent period in which Ca" levels do not appreciably change, followed by a rise in intracellular Ca“. Both responses are characterized by a falling phase where fluorescence decreases either linearly (neurotransmitter) or decays exponentially (IPz) to resting levels. Bradykinin stimulation elicits Ca wave propagation The activation of the B2 receptor with agonist elicits a Ca- wave in a cell injected with FFP-18. The Ca“ rise begins with a delay of 10-11 seconds after agonist application and spreads across the cell as a defined wave-front. An example is shown in Fig. 9. The cell is stimulated with bradykinin which invokes a Ca" wave beginning in the soma and spreading toward the growth cone. A second wave originates in the growth cone and propagates toward the soma. Wave speed is determined by measuring the time difference as a wave front passes two points in the cell. The data suggests that each wave front travels uninterrupted for at least 30um at a speed of 42um/s. Upon collision, the two waves annihilate each other (arrow). Annihilation is consistent with the proposed theory of an active process underlying wave propagation through an excitable medium [Wang et al., 19951. Flash photolysis of caged IPz abolishes wave propagation The activation of the IPz receptor through flash photolysis of caged IPz does not lead to wave propagation (Fig. 10). Following photolysis (time-O), the change in fluorescence occurs throughout the cell indicating that a Ca“ wave does not propagate. This result is consistent with the working model of wave propagation that assumes the IPz receptor is distributed throughout the cell, and not localized to a particular area. DISCUSSION Ca indicators exhibit unique decay phases The use of FFP-18 as a Ca“ indicator is advantageous in allowing one to monitor changes in Ca near intracellular membranes. However, its high affinity for Ca“ causes it to reach saturation well before the Ca" signal peaks during stimulation with bradykinin. In contrast, mag¬ fura-2, a low-affinity Ca indicator, presents the advantage of displaying spectral shifts at high Ca“ concentrations, allowing one to better resolve peak intracellular Ca. The difference in binding affinity between these two indicators leads to fluorescence decay patterns that are unique to the indicator following neurotransmitter stimulation. The slow decay to resting levels observed in a cell injected with FFP-18 and stimulated with bradykinin (Fig. 1) suggests that FFP-18 reaches saturation well before maximum concentrations of intracellular Ca“ (2uM) are reached. Even as Ca continues to decrease and return to resting levels, Ca remains well above FFP- 18 saturation concentrations for a significant period of time, leading to the slow apparent decay. FFP-18 is therefore better employed as an indicator when changes in Ca- are small (nanomolar range). Mag-fura-2 exhibits a rapid exponential decay to resting levels following attainment of peak [Ca (Fig. 2). The indicator's low affinity for Ca allows it to achieve better resolution of the 2uM peak in Ca following stimulation with bradykinin, thus making it an indicator of choice in imaging experiments where changes in intracellular Ca“ are large (micromolar range). Flash photolysis of caged IPz eliminates latency Stimulation of neuronal cells with the neurotransmitter bradykinin results in a latent period as long as 30 seconds in duration prior to release of Ca- from IPz receptor-regulated Ca storage compartments in the ER (Fig. 1-2). By direct release of IPz into the cytosol using flash photolysis, this latency is shown to be eliminated (Fig. 3-4). Within 200ms of photolysis, intracellular [Ca begins to increase, reaching peak Ca" levels within 1-2 seconds, following which levels decay exponentially. The time needed to reach half decay was measured to be 4.06s. This decay time most likely correlates to the degradation time of IP3. This compares favorably with biochemical measure of IPz degradation of approximately 9 seconds WWang et al., 19951 Prior to this half decay point, it is likely that several IPs receptors are still being activated by IP; molecules remaining in the cytosol. Past the half decay point, it is postulated that all IP3 released by flash photolysis has degraded, IPz receptors are inactive, and Ca- levels slowly return to resting levels. The results suggest that the latency observed prior to Ca release is characteristic of the pathway (Fig. 6). They further suggest that neither the time of IPz diffusion from its site of production to its receptors on the ER nor the time to Ca“ release following IPz receptor activation significantly contribute to the latency observed following stimulation with neurotransmitter. It is postulated that the latency arises earlier in the phosphoinositide signaling pathway, perhaps at the level of IPz formation through hydrolysis of phosphotidyl inositol 4,5 bisphosphate (PIP2) by phospholipase C (PLCB1). Cooperativity at the IP; receptor In this set of studies, the exact delay to Ca“ release from storage pools could not be resolved due to limitations in the fluorescence video imaging equipment. In particular, the 200ms delay following photolysis before imaging is accounted for by the 10Oms shutter speed as well as delay associated with camera response following shutter reopening (see Materials and Methods). To avoid such limitations, a rapid photodetector such as a photodiode or PMT needs to be employed. Research on the IPz receptor suggests that the receptor exhibits the property of cooperative binding [Meyer et al., 1988). The theory states that the binding of one IPs molecule to the IPz receptor facilitates the binding of other IP3 molecules. In order for the receptor to activate and thus serve as a channel for Ca“ release into the cytosol, 3 to 6 molecules of IPz need to be bound. The highly cooperative opening of Ca" channels by nanomolar concentrations of IPz enables cells to detect and amplify extremely small changes in the concentration of this intracellular messenger in response to various stimuli. The results from the uncaging experiments performed in this study support the theory of cooperativity at the IPz receptor. Release of relatively high intracellular concentrations of IP; (100nM) by flash photolysis results in a rapid increase in intracellular [Ca. Taking cooperative binding into consideration, it is concluded that the undocumented portion of the rising phase due to the speed limitations of the imaging equipment (see Materials and Methods) represents the lower foot portion of the sigmoidal curve characteristic of cooperative binding Gradual rising phase following flash photolysis suggests regeneration An averaged cellular response to flash photolysis of caged IPz exhibits a rapid increase in [Ca following uncaging, but a noticeably slower rise (1-2 seconds) to peak Ca levels (Fig. 4). This gradual rise to maximum intracellular [Ca suggests a regenerative process at the level of IPz receptor activation. Rather than achieving peak cytosolic Ca levels immediately, the peak is attained through repeated activation of IP3 receptors. Researchers have theorized that submicromolar concentrations of Ca“ can cause IPz receptors to reach threshold by altering the receptor's binding affinity for IPz, thus activating the receptors and releasing additional Ca- into the cytosol. This theory of a Ca“-induced Ca“ release at the IPz receptor (Finch et al., 1994 can explain the apparent regenerative process observed following uncaging of IP3. Flash photolysis of caged IPz abolishes wave propagation The working model of Ca“ wave propagation in neuronal cells suggests an active process underlying wave propagation. This process may involve an interaction between cytosolic Ca- and IPz receptors at the wave front [Wang et al., 1995]. The model is based on the assumption that IPz receptors are distributed throughout the entire cell, and not localized to a particular area. Stimulation with the neurotransmitter bradykinin elicits Ca" wave propagation in neuronal cells (Fig. 9). Cells injected with caged IPz and exposed to flash photolysis, however, do not propagate Ca“ waves (Fig. 10). The result indicates that the model's underlying assumption of a wide cellular distribution of IPz receptors is correct. The result further suggests that Ca- waves travel through this excitable IPz receptor rich medium. Two mechanisms underlying the active wave propagation can be postulated. If IPz is produced at the wave front, it can act to sustain propagation through activation of subsequent IPz receptors down the length of the cell. Alternatively, if Ca" interacts with IPs receptors as the model suggests, it can invoke a Ca“-induced Ca“ release at the wave front to sustain propagation through the cell. Future investigation It has been suggested that IPz needs to reach sufficient threshold levels in order to activate IPz receptors and subsequently cause Ca“ release into the cytosol (Parker, 1988). In order to measure and quantify this hypothetical IPz threshold, continued experiments using flash photolysis of lower concentrations of caged IPs need to be conducted. Furthermore, it would be equally beneficial to stimulate cells with neurotransmitter, uncage IPz at varying intervals during the latent period, and measure changes in latency to Ca“ release. Such studies could potentially determine if it is [P itself which regulates and determines latency. In addition, other steps in the phosphoinositide signaling pathway merit further investigation to determine their roles in the latency to Ca“ release following neurotransmitter stimulation. Essential steps to investigate are PIP2 hydrolysis, PLCBI activation, and Gyii turnover. Finally, to determine the possible coagonist relationship between cytosolic Ca and IP- receptors, one would measure changes in cytosolic [Ca via fluorescence video microscopy in response to flash photolysis of caged Ca“ compounds (DM-nitrophen, NITR-5) REFERENCES 1. Albritton N, Meyer T, Stryer L. Range of messenger action of calcium ion and inositol 1,4,5- trisphosphate. Science. 258: 1812-1815, 1992 2. Coggan JS, Thompson SH. Cholinergic modulation of Ca response to bradykinin in neuroblastoma cells. [In Press 3. Coggan JS, Thompson SH. Intracellular calcium signals in response to bradykinin in individual neuroblastoma cells. American Journal of Physiology. 269: C841-848, 1995 4. Finch E, Turner T, Goldin S. Calcium as a coagonist of inositol 1,4,5-trisphosphate-induced calcium release. Science. 252: 443-446, 199 5. Finch E, Goldin S. Calcium and inositol 1,4,5-trisphosphate-induced Ca“ release. Science. 265: 813-815, 1994 6. Gilkey JC, Jaffe LF, Ridgway EB, Reynolds GT. A free calcium wave traverses the activating egg of the medaka, Oryzias latipes. Journal of Cell Biology. 76: 448-466, 1978 7. Hartzell HC. Mechanisms of slow postsynaptic potentials. Nature. 291: 539-543, 1981 8. Meyer T, Holowka D, Stryer L. Highly cooperative opening of calcium channels by inositol 1,4,5-trisphosphate. Science. 240: 653-655, 1988 9. Miledi R, Parker I. Latencies of membrane currents evoked in Xenopus oocytes by receptor activation, inositol trisphosphate and calcium. Journal of Physiology. 415: 189-210, 1988 10. Parker I, Miledi R. Inositol trisphosphate activates a voltage-dependent calcium influx in Xenopus oocytes. Proceedings of the Royal Society of London. B231: 27-36, 1987 11. Parker I, Ivorra I. Localized all-or-none calcium liberation by inositol trisphosphate. Science. 250: 977-978, 1990 12. Parker 1. A threshold level of inositol trisphosphate is required to trigger intracellular calcium release in Xenopus oocytes. Journal of Physiology. 407: 95P, 1988 13. Rhee SG, Suh PG, Ryu SH, Lee SY. Studies of inositol phospholipid-specific phospholipase C. Science. 244:546-550, 1989 14. Vorndran C, Minta A, Poenie M. New fluorescent calcium indicators designed for cytosolic retention or measuring calcium near membranes. Biophysical Journal. 69: 2112-2124, 1995 15. Wang SS, Alousi AA, Thompson SH. The lifetime of inositol 1,4,5-trisphosphate in single cells. Journal of General Physiology. 105: 149-171, 1995 16. Wang SS, Thompson SH. Local positive feedback by calcium in the propagation of intracellular calcium waves. Biophysical Journal. 69: 1683-1697, 1995 FIGURE LEGENDS FIGURE 1: Calcium signal in response to bradykinin with high-affinity indicator. Example of the dynamics of Ca“ release from a cell injected with FFP-18, K salt (ImM micropipette concentration) and stimulated with bradykinin (100nM). Agonist is delivered at time-O, followed by a 10-11 second latent period in which [Ca do not appreciably change. The latency is followed by a 20 fold increase in [Ca over a 2-3 second time period. Intracellular Ca then exhibits a slow decay, presumably toward resting levels. FIGURE 2: Calcium signal in response to bradykinin with low-affinity indicator. Example of the dynamics of Ca“ release from a cell loaded with mag-fura-2/AM (SuM) and stimulated with bradykinin (100nM). Following stimulation (time-O), [Ca*1 do not appreciably change for a period of 6-7 seconds. The latent period is followed by a 25 fold increase in cytosolic Ca over a time interval of 2-3 seconds in which peak Ca“ levels are resolved. Following attainment of peak [Ca-, a rapid decay to resting levels is observed. FIGURE 3: Calcium signal in response to flash photolysis of caged IPz. Cells injected with caged IPz plus fluo-3 (ImM micropipette concentrations) exhibit an instantaneous increase in [Ca following flash photolysis. The flash used to uncage IPz is represented by the sudden decrease in fluorescence caused by shutter closing. Cytosolic [Ca“ begins to rise within 200ms following exposure to the flash, and attain peak levels within 1 second following flash. FIGURE 4: Average response to flash photolysis of caged IPz. An average response of cells (n-3) injected with caged IPz plus fluo-3 exhibits an immediate increase in cytosolic Ca following flash photolysis. Rise begins within 200ms following flash exposure, with peak levels gradually attained 1-2 seconds later. FIGURE 5: Falling phase kinetics following flash photolysis of caged IPz. Following attainment of peak cytosolic [Ca, fluorescence decays exponentially to resting levels. The solid line represents actual fluorescence decay while the dashed line represents an exponential function curve-fitted to the data. FIGURE 6: Rising phase kinetics of [Cd in response to flash photolysis of caged IPz. Ca' imaging was not documented for the initial 200ms following flash photolysis (time interval indicated by vertical, dashed lines). The time to shutter reopening as well as the delay response of the camera accounts for this delay period. Recording begins (*) when cytosolic Ca is already near maximum, which is attained within 1 second following recording. FIGURE 7: Average rising phase kinetics of Ca1 in response to flash photolysis of caged IPz. An average kinetic response of cells (n-3) exposed to flash photolysis shows the 200ms blanking of the recording (indicated by vertical, dashed lines), but a slightly longer time to peak [Ca (2-3 seconds) compared to the single cell response. FIGURE 8: Latency following flash photolysis of IPz versus bradykinin stimulation. The solid line represents a cell injected with caged IPz plus fluo-3 (ImM micropipette concentrations) and stimulated by flash photolysis (indicated by drop in fluorescence). The dashed line represents the same cell stimulated with a saturating concentration of bradykinin (100nM) moments later. Flash photolysis of IPz results in a rise in [Ca within 200ms of uncaging. Stimulation with bradykinin (time-O) results in a 5-7 second latency before Ca“ release in which cytosolic Ca does not appreciably change. The peak level attained following bradykinin stimulation is lower than observed following neurotransmitter stimulation due to insufficient time to refilling of Ca storage pools as well as IPz receptor desensitization. Following peak Ca, fluorescence values decay either linearly (neurotransmitter) or exponentially (IPz) to resting levels. FIGURE 9: Calcium wave propagation in bradykinin stimulated cells. Ca rise begins with a delay of 10-11 seconds after agonist stimulation (time-O) and spreads across the cell in a defined wave-front (varying colors represent varying levels of fluorescence). Two separate waves originate at opposite ends of the cell (soma and growth cone) and propagate toward one another at 42um/s. Upon collision, the waves annihilate each other (arrow). FIGURE 10: Flash photolysis of IP3 does not cause wave propagation. Following flash photolysis (time-O), fluorescence (black) increases evenly throughout the cell, indicating simultaneous Ca“ release and a lack of wave propagation. FIC 1 1.30 1.25 1.20 1.15 1.10 1.05 S — 1.00 095 0 2 4 6 8 10 12 14 16 18 20 22 24 Time (seconds) FIGURE 2 1.225 1.200 1.175 1.150 1.125 1.100 1.075 1.050 1.025 0 1000 0.975 + 46 8 10 12 14 16 18 20 22 24 Time (seconds) FIGURE 3 1.075 1.050 1.025 1.000 0.975 0.950 - Flash 0.925 + 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Time (seconds) FIGURE 4 1.07 1.06 A 1.05 - 1.04 1.03 1.02 1.01 1.00 0.99 e 0.98 0.97 - 0.96 Flash 0.95 + 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Time (seconds) FIGURE 5 1.075 1.050 1.025 1.000 0.975 ahehetie 0.950 0.925 0.900 — ka va vava kvak- 1.5 3.0 4.5 6.0 7.5 9.0 10.5 12.0 13.5 15.0 Time (seconds) 1.075 1.065 1.055 1.045 1.035 1.025 1.015 1.005 0.995 0.985 0.975 + 0.0 0.5 1.0 FIGURE 6 VV — k kava- 1.5 2.0 2.5 3.0 3.5 Time (seconds) 1.075 - 1.065 1.055 1.045 1.035 1.025 1.015 1.005 0.995 0.985 0.975 0.0 0.5 1.0 NA FIGURE 7 1.5 2.0 Time (seconds) V 2.5 3.0 3.5 FIGURE 8 1.150 N 1.125 W 1.100 - V .* 1.075 . . 1.050 Hene. 1.025 ........ 1.000 0.975 0.950 - 0.925 0.900 0.875 Flash 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Time (seconds) FIGURE 9 k 11 FIGURE 10 Fa 14 38 Distance along axon (uni)