INTRODUCTION It has been shown by Stephens and his co-workers that many marine invertebrates can accumulate amino acids from ambient seawater (Stephens, 1962, 1963, 1964, 1967, 1968; Stephens and Schinske, 1961; Stephens and Virkar, 1966; North and Stephens, 1961; and Virkar, 1966). The present study further examines some of the characteristics of amino acid uptake and utilization in the cirratulid polychaete, Cirriformia spirabrancha. The amino acid glycine was used for this study because it is the most abundant free amino acid in seawater. Studies were made to determine the rate of concentration, the rate of incorporation into alcohol insoluble material, the total rate of uptake, and the anatomical sites of amino acid uptake. MATERIAL AND METHODS Worms were collected from sandy areas just south of Fisherman's Wharf, Monterey, California and stored in the laboratory under simulated natural conditions until used, usually between one and five days after collection. The worms were washed free of external mucous and sand, blotted on filter paper to remove excess water, weighed to the nearest 10 mg. and placed in room temperature seawater (20-22°c). The wet weight varied between.14 and.40 grams. Various concentrations of glycine solution were made in artificial seawater by dissolving C glycine (Sigma Chemical Corp.) in a constant amount of glycine-UL-Ct (ICN, specific activity 76.0 m0/mM). In a number of experiments, indicated in the figure legends, glycine anhydride (NBC) was mistakenly used in place of the 18. glycine. Each worm was placed in 10ml of one of these solutions which ranged in concentration from .65x10-0 M/L to 10-3 "/L. After a stipulated period of time, the worm was washed for 30 seconds in seawater, homogenized in a tissue homogenizer in 20 volumes of 80% ethanol, and then centrifuged for 10 minutes in a clinical centrifuge. The supernatant was saved while the pellet was washed again in 80% ethanol, centrifuged and dissolved in 10 volumes of formic acid. O.lml aliquots of the supernatant and dissolved pellet were then placed on separate planchets, spread with 0.5ml formic acid, evaporated under an infra-red lamp, and radioactivity measured with a thin window Geiger-Muller detector. Radioactivity of each glycine-seawater solution was also measured in this manner after plating 0.lml of the solution with 0.5ml 80% ethanol and evaporating in a drying oven. All samples were taken in triplicate and corrections for background and quenching have been included in the data presented. RESULTS The three major parameters of uptake are the concentration of free glycine in the worm (alcohol-soluble radioactivity), the rate of incorporation of glycine into proteins and nucleic acids (alcohol-insoluble radioactivity), and the total rate of uptake (total radioactivity). Figurell shows that uptake of free glycine is linear for at least 60 minutes, and that rate of incorporation and total rate of uptake are linear for the two hour period. Since the worms differed in weight, it was necessary to find the relation between wet weight and total rate of uptake. When wet weight was plotted against total rate of uptake. (figure 2), it was found that a linear relationship existed. The total rate of uptake increases as the external glycine concentration increases, up to an external concentration of 5 x10- "/L. At this concentration the rate of uptake is no longer affected by an increase in external concentration (figure 3). This uptake curve is characteristic of a transport system. Other experiments indicate that the gut is not involved in uptake, since ligation of the head and tail regions had no effect on uptake rate. This suggests the major sites of uptake are through the body wall and tentacles. Table 1 compares uptake of the body and tentacles on a weight basis. In this experiment the worms were incubated in C+ glycine for the indicated periods of time. At the end of the incubation period the tentacles and body were separated from each other and the uptake determined. The results show that the tentacles are five times more effective in uptake, on a weight basis, than is the body wall. DISCUSSION The uptake vs. wet weight relation in C. spirabrancha can be expressed as Uptake - kW, where k is a constant and W is wet weight. This means that uptake varies directly with 59 the volume of the worm, where one would expect uptake to vary directly with the surface area. One explanation for this is that surface area also varies directly with volume or weight. This is not too hard to imagine if one considers that this worm and its tentacles have a great capacity for stretching. This means that it has a great surface area per volume and also that a change in volume is mostly indicated in a change in length which is proportional to surface area. Thus it seems that surface area might indeed vary directly with volume over the range of weights used in this study. Stephens (1964) showed that the radioactivity of the alcohol-soluble fraction of an extract of Clymenella Torquata resided in glycine alone. This is probably true in the present experiments also, especially since the incubation periods were relatively short. The total rate of uptake and the rate of incorporation of alcohol-insoluble material are linear for at least 120 minutes, whereas the rate of concentration of free glycine slows down with time. There are two explanations for the rate of concentration slowing down with time. One is that the enzyme system may not be capable of increasing the concentration gradient any further and thus the rate of concentration will level off. The other is that the worm has probably markedly depleted the external concentration of glycine over the two hour period and this low external concentration may be a limiting factor for the transport system. This latter explanation seems quite plausible since the worm was in only lOml of solution for two hours. The total rate of uptake vs. concentration relation or C. spirabrancha is similar to those of other marine invertebrates studied by Stephens and his co-workers. Stephens (1968) gives the typical ranges of Vmax and Km for the organisms he has studied. Vmax (maximum rate of uptake) ranges between 10-7 and 10-5 moles/g per hour and Km (concentration at which a half maximal rate of uptake occurs) ranges between 10-4 and 10-5 M/L. Calculations derived from the data of figure 3, depicted in figure 4, show that C. spirabrancha has a Vmax of 2.4 x10-6 M/g per hour and a Km of 1.2x10-4 "/L, both well within the ranges given by Stephens. 6 SUMMARY Studies were made on amino acid uptake into alcohol soluble and alcohol-insoluble products by the polychaete, Cirriformia spirabrancha. A radioactive tracer method was used employing glycine-UL-C+. The uptake vs. wet weight relationship was linear, and can be expressed as Uptake - kW. The body wall and tentacles were the major areas of uptake, with the tentacles having a rate five times as great as the body on a weight basis. Uptake vs. external concentration was also studied. The Vmax was 2.4 x 10-6 M/g per hour and the Km was 1.2 X10-4 M/L. ACKNOWLEDGEMENTS would like to extend my gratitude to Dr. D. Epel and the faculty and staff of Hopkins Marine Station for making this project possible. This work was supported in part by the Undergraduate Participation Program of the National Science Foundation Grant GY-4369. BIBLIOGRAPHY North, B. B., and G. C. Stephens. 1967. Uptake and assimilation of amino acids by Platymonas. Biol. Bull. 133:391-400. Stephens, G. C. 1962 Uptake of organic material by aquatic invertebrates. I. Uptake of glucose by the solitary coral, Fungia scutaria. Biol. Bull. 123:648-659. Stephens, G. C. 1963. Uptake of organic material by aquatic invertebrates. II. Accumulation of amino acids by the bamboo worm, Clymenella torquata. Comp. Biochem. Physiol. 10:191-202. Stephens, G. C. 1964. Uptake of organic material by aquatic invertebrates. III. Uptake of glycine by brackish water annelids. Biol. Bull. 126:150-162. Stephens, G. C. 1967. Dissolved organic material as a nutritional source for marine and estuarine invertebrates. p. 367-373. In G. H. Lauff, (ed.), Estuaries. AAAS. Washington, D.C. Stephens, G. C. 1968. Dissolved organic matter as a potential source of nutrition for marine organisms. Amer. Zool. 8:95-106. Stephens, G. C., and R.A. Schinske. 1961. Uptake of amino acids by marine invertebrates. Limnol. Oceanog. 6:175-181. Stephens, G.C., and R. A. Virkar. 1966. Uptake of organic material by aquatic invertebrates. IV. The influence of salinity on the uptake of amino acids by the brittle star, O 9. Ophiactis arenosa. Biol. Bull. 131:172-185. Virkar, R. A. 1966. The role of free amino acids in the adaptation to reduced salinity in the sipunculid Golfingia gouldii. Comp. Biochem. Physiol. 18:617-626. C FIGURE LEGENDS Figure 1: Curve 1 gives the total rate of glycine uptake over a two hour period; curve 2 shows the rate of incorporation of free glycine into alcohol-insoluble material; curve 3 shows the concentration of free glycine in the worm. External glycine concentration is .65 X10-° M/L with glycine anhydride at a concentration of .5 X10-6 M/L. Figure 2: The rate of uptake (in counts per minute per worm) vs. the wet weight of the worm in grams. External glycine concentration .65 X10-° M/L with glycine anhydride at a concentration of ,5 X10-6 M/L. Incubation time was 15 min. Figure 3: The effect of external concentration vs. internal concentration in moles per liter. External concentration varied from .65 x10 ° to 10-2 M/L. Incubation time was 15 min. Figure 4: The reciprocal of external concentration vs. the reciprocal of internal concentration (M/L/15 min.). The slope of the line indicates Km and the intercept indicates Vmax. This figure was calculated from figure 3. Table 1: A comparison of rate of concentration on a weight basis of glycine between the tentacles and body over a 15 minute period. The numbers indicate 10- /9 . The external glycine concentration was .65 X10° M/L with glycine anhydride at a concentration of .5X10-0 M/L. . 163 0 10 Millimeters 30 120 Equre 1 0 3 . 12-188 F H C 10 Millimeters to 2 Fiqure 0 0 20 Wet weight oas) ++++ ++ 30 10 . 12-188 0 H 10 It m/ 10 Figure 0 124185 16 2.0 1.8 12 1.0 meters to the Centim 5 0 + igure 4 — H 0 TENTACLES BODY min. . TABLE 1 2 min. .41 .12 5 mi 4.7 .92 10 min. 5.3 T 5 min. 8.1 1.2