Schneider Lipid and Glycogen Content INTRODUCTION Work done on lipid and glycogen metabolism in poly¬ chaetes is scarce. However, Giese (1966) reports many studies on other invertebrates. Table 1 presents the results of studies on glycogen and lipid contents of various polychaetes. Changes in the glycogen and lipid of several annelids and the sipunculids Phascolosoma agassizii and Phascolosoma gouldii have been in- vestigated. Terebella lepidara showed a marked decrease in body wall lipid content after ten days of starvation. Arenicola marina showed a body wall lipid content increase after six weeks of starvation and a four fold increase in the gut lipids during the same period. Dales (1957a) Von Brand (1927) studied glycogen contents in polychaetes and concluded that the substance in the worms he studied is used in times of oxygen stress. Scheer (1969) reports on conversion of glycogen to lactic acid under anaerobic conditions in oligochaetes. Dales (1958) found that Arenicola marina uses its glycogen stores during anaerobiosis, while Owenia fusiformis, which has a lower glycogen content, does not show an appreciable depletion of glycogen reserves. Instead, Dales suspects a reduction in metabolic rate. No evidence of lactic or pyruvic acid was found. Towle and Giese (1966) measured the effect of starvation on Phascolosoma agassizii. The original carbohydrate level of 4.1% and glycogen of .8% (dry weight) did not appreciably de¬ Lipid and Glycogen Content Schneider crease. Instead, the lipids were metabolised and fell from 4.1% to 3.3% in seventeen days and to 2.7% in seventy-one days. Wilbur (1947) has done starvation studies on the sip¬ unculid Phascoloma gouldii. After four weeks the lipid content decreased from 3.86% to .8% but the muscle lipid content in¬ creased from 1.32% to 2.02%, possibly indicating the utilisation of proteins found there. The above data posed an interesting question. Some polychaetes such as Terebella lepidara showed decreases in lipid contents during starvation while increases in lipid con¬ tents were noted in Arenicola marina. Thus, the metabolism of lipids during starvation did not seem to follow any general pattern. Neither did the usage of glycogen during starvation seem to be a well explored topic. The study reported here is an investigation of lipid and glycogen content of the polychaetes, Myxicola infundibulum (Renier 1804), Cirriformia luxuriosa (Moore 1904), Halosydna brevisetosa (Kinberg 1855), and Phragmatopoma californica (Fewkes 1899), and the effect of short term starvation on these reserves. MATERIALS AND METHODS All animals were collected from the Monterey area in central California. M. infundibulum and H. brevisetosa were collected subtidally at the Monterey marina. P. cali¬ fornica was taken by chiseling a portion of a colony found past the east end of Aggassiz beach at Hopkins Marine Station. C. luxuriosa was taken from the mud around the roots of the Schneider Lipid and Glycogen Content eel grass Phyllospadix. The worms were either analysed fresh from the field or deprived of food as follows. M. infundibulum and C. luxuriosa were placed in a plastic pan supplied with running, glass fiber filtered sea water at 12.0-13.5° C. Sixteen worms were analysed immediately or after one and two weeks of starvation. Each of sixteen worms of each species was homogenised in 1 ml of distilled water per wet weight gram of worm except for P. californica. Sixteen samples of five to eight P. californica were substituted because of their small size. Lipids were first extracted using three ten ml portions of a 50:50, volume to volume, mixture of 95% ethyl alcohol and diethyl ether. The insoluble material was removed by centrifuging at 2000 rpm for 10 minutes. The ethanol-ether was poured into a beaker, evaporated to dryness, and re-extracted with two five ml portions of chloroform. The chloroform was then poured into a pre-weighed pan and evap¬ orated to dryness. The material insoluble in ethanol-ether was then assayed for glycogen by the method of Somogyi (1934). Two ml of 50% sodium hydroxide were added for each gram of original tissue and digested for three hours at 100° C. After digestion the alkaline mixture was centrifuged for 10 minutes at 2000 rpm. The clear alkaline fluid was decanted and the remaining matter was washed with two ml of distilled water for each gram of tissue, shaken, and centrifuged for 10 minutes at 2000 rpm. This fluid was then united with the first and one ml of 95% ethanol added for each two ml of fluid. The glycogen was allowed to precipitate overnight. Lipid and Giycogen Content Schneider 4 The next day the carbohydrates were collected by centrifugation at 2000 rpm for fifteen minutes, the supernatant poured off, and the pellet washed with 95% ethanol. Total glycogen was determined colourimetrically by the phenol-sulphuric acid method of Dubois (1956). Values obtained were compared with a standard curve prepared with glucose, RESULTS The results of the lipid and glycogen determinations are given in Table 2 as the mean and standard deviation of the sixteen samples of worms. In general the levels of these materials correspond to the values reported for other polychaetes in Table 1. The starvation experiments carried out with C. lux¬ uriosa had a range of glycogen contents at time O of .019% to 19%. See Figure 1. The mean was .054% +.042. After one week the range was from .021% to .11% with a mean of .064% + .026. After two weeks of starvation the glycogen content ranged from .020% to .065% with a mean of .042% +.013. The decrease over the last week was significant at p less than .02 using a "t" test. The range of values converged on a lower limit in each case of.019%. The lipids in C. luxuriosa showed an increase over two weeks of starvation; see Figure 2. At O time the lipid content ranged from 1.6% to 2.8% with a mean of 2.24% + .41. After one week the values ranged from 1.9% to 3.6%. The mean Schneider Lipid and Glycogen Content value was 2.69% + .47. This increase is significant at p less than .007. After two weeks the lipid content ranged from 2.1% to 3.1% with a mean of 2.56% +.36. This was also significantly higher than at O time with p less than.013 but not significantly different from the value at one week. For M. infundibulum, the glycogen was found to range from .021% to .069% of wet body weight. The mean was found to be .043% + .015. One week of starvation produced a range of .014% to .064% glycogen with a mean of .034% +.021; see Figure 3. Two weeks of starvation showed the worm's glycogen to range from .014% to .079% and the mean being .037% +.020. None of these values showed any statistically significant change over the two week period. The lipids of M. infundibulum initially ranged from 2.5% to 3.8% with a mean of 3.28% +.41. One week later the lipids comprised from 2.3% to 4.4% of body weight, the mean being 3.22% + .67; see Figure 4. After two weeks without nourishment, the worms showed lipid contents of from 2.0% to 3.8% with a mean of 2.84% + .53. The decrease in lipid content in M. infundibulum is significant at p less than.02. DISCUSSION The subtidal worms Halosydna brevisetosa and Myxicola infundibulum both show the two highest lipid contents and the two lowest glycogen levels. The intertidal worms, Phragmatopoma californica and Cirriformia luxuriosa show lower lipid contents and slightly higher glycogen contents. Whether this is of adaptive significance or just coincidence can not be deter¬ Schneider Lipid and Glycogen Content mined at this point. The levels of glycogen and lipid in these worms corresponded to levels reported in other polychaetes. Cirriformia luxuriosa seems to be relying on glycogen and some other reserve material, possibly protein, to survive periods of starvation. During the two week period the glycogen content of the worms decreased, implying the metabolism of this energy reserve. The upper limit of the ranges also consistently decreased over the course of starvation while the lower limit remained constant. This indicates a basic body level of glycogen which may not be metabolised. As the worms starve, they seem to use up their glycogen to the point where it comprises.019% of wet body weight. The lipid content as a percentage of body weight appear¬ ed to increase over the period of two weeks. This can be explained in one of two ways. Either the annelid has syn¬ thesised lipids or has used some other reserve to a greater extent than lipids. The latter hypothesis seems the more likely. Unless there is a decrease in metabolic rate during starvation, something other than glycogen must be the substrate of this metabolism because the decrease in glycogen over the two week period is small, 120 micrograms/gram of worm. In Myxicola infundibulum there was no significant change in glycogen during the period of starvation. However, there did seem to be a lower limit to glycogen content here as in Cirriformia luxuriosa. Myxicola infundibulum did show a significant decrease in lipid levels over the two week period. This decrease of .44% of body weight in lipid content is 6 Schneider Lipid and Glycogen Content attributed to lipid utilisation by the worm. Thus, it appears that this worm does not appreciably utilise glycogen at the onset of starvation, but instead metabolises its lipids for energy. It seems that these polychaetes do not rely solely on glycogen as an energy reserve. One species, Cirriformia luxuriosa, seems to call upon proteins or some other reserve to make up for an energy deficit during early starvation. Another polychaete, Myxicola infundibulum, seems to rely upon lipid stores at the onset of starvation. This is entirely consistent with the previous observations of Dales (1957a), Towle and Giese (1966), and Wilbur (1947). Lipid and Glycogen Conter Schneider SUMMARY 1. Lipid and glycogen content determinations were done on Myxicola infundibulum, Cirriformia luxuriosa, Halosydna brevisetosa, and Phragmatopoma californica collected from the Monterey Bay area of central California. Myxicola infundibulum and Cirriformia luxuriosa were starved for two weeks and their lipid and glycogen contents assayed. Myxicola infundibulum appears to rely on stored lipids at the onset of starvation. Cirriformia luxuriosa appears to use some other reserve at the onset of starvation. ACKNOWLEDGEMENTS I would like to thank Dr. John Phillips for his invaluable help and encouragement during the course of this project. Lipid and Glycogen Contents Schneider 9 REFERENCES Brand, T. von 1927 2. Vergleich Physiol. 5: 643-698 Preliminary Observations on the Role Dales, R. P. 1957a of the Coelomic Cells in Food Storage and Transport in Certain Polychaetes. J. Mar. Biol. U. K. 36: 91-110 Feeding in Sabellids and Serpulids. Dales, R.P. 1957b J. Mar. Biol. U.K. 36: 309-316 Survival of Anaerobic Periods by two Dales, R.P. 1958 Intertidal Polychaetes: Arenicola marina and Owenia fusiformis. J. Mar. Biol. U.K. 37: 521-529 J.K. Hamilton, P.A. Rebers, & F. Smith 1956 Dubois, M., K.A. Giles, Colorimetric Method for Determination of Sugars and Related Substances. Analyt. Chem. 28: 350-356. Constitution et Proprietes Physico Fremiet, E.F. 1929 Chemiques des Eleocytes D'Amphritrite johnstoni (Malmgren). Protoplasma 5: 321-337 Lipids in Marine Invertebrates. Giese, A.C. 1966 Physiological Review 46: 244-298 Chemical Zoology Academic Press, Scheer, B. & M. Florkin New York, 1969 The Solubility and Preparation of Somogyi, M. 1934 Phosphorous and Nitrogen Free Glycogen. J. Biol. Chem. 104: 245-253 Biochemical Changes During Towle, A. & A.C. Giese 1966 Reproduction and Starvation in the Sipunculid Worm Phascolosoma aggassizi. Comp. Biochem. Physiol. 19: 667-680 Effect of Prolonged Starvation on the Wilbur, C.G. 1947 Lipids in Phascolosoma gouldii. J. Cell. Comp. Physiol. 29: 179-183 Wilbur, C.G. & W.M. Bayors 1947 A Comparative Study of the Lipids in Some Marine Annelids. Biol. Bull. 93: 99-101 Table 1 Species % Lipid % Glycogen Amphritrite johnstoni wet wt. .8%- 4% 1.2% Nereis diversicolor wet wt. 1.43% -1.73% Nereis pelagica wet wt. 2.17% Glycera americana wet wt. 2.75% Amphritrite ornata wet wt. 3.15% Arenicola marina wet wt. 1.22% rite Amphri johnstoni dry wt. 27.6% Nere pelagica 3.81% wet wt. Arenicola marina wet wt. .54% Phoronopsis viridis 4.9% dry wt. Sabella starki magnificans 1.5% dry wt. 9.2% Glycera rugosa dry wt. 8.3% 1.4% Reference Dales (1957a) Dales (1957a) Wilbur & Bayors (1947) Wilbur & Bayors (1947) Wilbur & Bayors (1947) Wilbur & Bayors (1947) Fremiet (1929) von Brand (1927) von Brand (1927) Giese (1966) Giese (1966) Giese (1966) Table 2 Lipid and Glycogen Content species % ipid %o glycogen Cirriformia 054% -042 2.24%-41 luxuriosa Myxicola Q43%- 015 3.28%—41 infundibuum Halosydna 3.66% 51 018% - .008 previsetosa Phragma¬ 137%- 073 2.95%.60 topoma californica VALUES ARE MEAN PERCENT OF WET WEIGHT FOLLOWED BY STANDARD DEVIATIONS Figure 1. Change in the glycogen content of Cirriformia luxuriosa with starvation. Each point represents the total glycogen content of one worm expressed as a percent of wet weight. 20 18 16 14 12 00 08 glyc. 06 04 02 O0 e Figure 2. Change in lipid content of Cirriformia luxuriosa with starvation. Each point represents the total lipid content of one worm expressed as a percent of wet weight. 40 G.O lipid 2.0 1.0 o o o O o8 Weeks 2 0 Figure 3. Change in the glycogen content of Myxicola infundibulum with starvation. Each point represents the total glycogen content of one worm expressed as a percent of wet weight. 087 O6 glyc. 04 02 OO o 2 Weeks c Figure 4. Change in the lipid content of Myxicola infundibulum with starvation. Each point presents the total lipid content of one worm expressed as a percent of wet weight. 5.0 40 lipid O3.C 2.0 1.0 088 0 2 Weeks